Kinetics of thermal decomposition and hydrogen reduction of Cobalt compounds: A review
Pöyhtäri, Sonja; Heikkinen, Eetu-Pekka; Heikkilä, Anne (2025-02-13)
Elsevier
13.02.2025
Pöyhtäri, S., Heikkinen, E.-P., & Heikkilä, A. (2025). Kinetics of thermal decomposition and hydrogen reduction of Cobalt compounds: A review. Thermochimica Acta, 746, 179952. https://doi.org/10.1016/j.tca.2025.179952
https://creativecommons.org/licenses/by/4.0/
© 2025 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license ( http://creativecommons.org/licenses/by/4.0/ ).
https://creativecommons.org/licenses/by/4.0/
© 2025 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY license ( http://creativecommons.org/licenses/by/4.0/ ).
https://creativecommons.org/licenses/by/4.0/
Julkaisun pysyvä osoite on
https://urn.fi/URN:NBN:fi:oulu-202502261851
https://urn.fi/URN:NBN:fi:oulu-202502261851
Tiivistelmä
Abstract
Cobalt is an important transition metal that plays a critical role in the growing battery industry, and in hard metal applications and super alloys. Cobalt powder can be produced via solid-state hydrogen reduction of different cobalt compounds from which cobalt oxides have been widely studied since 1960s. Hydrogen is an efficient and environmentally friendly reductant and its utilization in metal refining is being increasingly studied. This paper presents an overview of important findings regarding hydrogen reduction kinetics of cobalt oxides alongside thermal decomposition kinetics of cobalt carbonates and hydroxides. This will assist researchers in the future to choose and modify hydrogen reduction parameters by identifying the factors affecting the overall reduction reaction of different cobalt compounds and characteristics of derived cobalt products.
Cobalt is an important transition metal that plays a critical role in the growing battery industry, and in hard metal applications and super alloys. Cobalt powder can be produced via solid-state hydrogen reduction of different cobalt compounds from which cobalt oxides have been widely studied since 1960s. Hydrogen is an efficient and environmentally friendly reductant and its utilization in metal refining is being increasingly studied. This paper presents an overview of important findings regarding hydrogen reduction kinetics of cobalt oxides alongside thermal decomposition kinetics of cobalt carbonates and hydroxides. This will assist researchers in the future to choose and modify hydrogen reduction parameters by identifying the factors affecting the overall reduction reaction of different cobalt compounds and characteristics of derived cobalt products.
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