'Schmidbaur gold chemistry' and beyond
Bezuidenhout, Daniela I.; Esterhuysen, Catharine; Dobrzanska, Liliana; Cronje, Stephanie; Raubenheimer, Helgard G. (2025-01-13)
De Gruyter
13.01.2025
Bezuidenhout, D., Esterhuysen, C., Dobrzańska, L., Cronje, S. & Raubenheimer, H. (2024). ‘Schmidbaur gold chemistry’ and beyond. Zeitschrift für Naturforschung B, 79(12), 549-577. https://doi.org/10.1515/znb-2024-0086
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© 2025 Walter de Gruyter GmbH, Berlin/Boston. This is an Accepted Manuscript of an article published by De Gruyter in Zeitschrift für Naturforschung B on 13 January 2025, available at https://doi.org/10.1515/znb-2024-0086. It is deposited under the terms of the Creative Commons Attribution-NonCommercial-NoDerivatives License (http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial re-use, distribution, and reproduction in any medium, provided the original work is properly cited, and is not altered, transformed, or built upon in any way. If you wish to use this manuscript for commercial purposes, please contact rights@degruyter.com.
https://creativecommons.org/licenses/by-nc-nd/4.0/
© 2025 Walter de Gruyter GmbH, Berlin/Boston. This is an Accepted Manuscript of an article published by De Gruyter in Zeitschrift für Naturforschung B on 13 January 2025, available at https://doi.org/10.1515/znb-2024-0086. It is deposited under the terms of the Creative Commons Attribution-NonCommercial-NoDerivatives License (http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits non-commercial re-use, distribution, and reproduction in any medium, provided the original work is properly cited, and is not altered, transformed, or built upon in any way. If you wish to use this manuscript for commercial purposes, please contact rights@degruyter.com.
https://creativecommons.org/licenses/by-nc-nd/4.0/
Julkaisun pysyvä osoite on
https://urn.fi/URN:NBN:fi:oulu-202501241338
https://urn.fi/URN:NBN:fi:oulu-202501241338
Tiivistelmä
Abstract
Hubert Schmidbaur has significantly influenced the field of gold chemistry. His work on preparing various aurocyclic digold compounds and studying their structures and reactivities has laid the foundation for unique applications in photophysics and homogeneous catalysis. The naming and characterization, both experimental and theoretical, of the aurophilicity phenomenon have led to numerous interdisciplinary applications. The emergence and development of dynamic gold chemistry in the excited state, exemplify this impact. Preparative methodologies, characterization techniques, and qualitative bonding theories have been tested through the rational preparation of ligated, element-centred gold clusters. The potential of this fascinating class of compounds remains largely untapped.
Hubert Schmidbaur has significantly influenced the field of gold chemistry. His work on preparing various aurocyclic digold compounds and studying their structures and reactivities has laid the foundation for unique applications in photophysics and homogeneous catalysis. The naming and characterization, both experimental and theoretical, of the aurophilicity phenomenon have led to numerous interdisciplinary applications. The emergence and development of dynamic gold chemistry in the excited state, exemplify this impact. Preparative methodologies, characterization techniques, and qualitative bonding theories have been tested through the rational preparation of ligated, element-centred gold clusters. The potential of this fascinating class of compounds remains largely untapped.
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