Preparation and characterisation of alkali-activated blast furnace slag and Na-jarosite catalysts for catalytic wet peroxide oxidation of bisphenol A
Hautamäki, Katariina; Heponiemi, Anne; Tuomikoski, Sari; Hu, Tao; Lassi, Ulla (2023-09-12)
Taylor & Francis
12.09.2023
Hautamäki, K., Heponiemi, A., Tuomikoski, S., Hu, T., & Lassi, U. (2024). Preparation and characterisation of alkali-activated blast furnace slag and Na-jarosite catalysts for catalytic wet peroxide oxidation of bisphenol A. Environmental Technology, 45(22), 4482–4494. https://doi.org/10.1080/09593330.2023.2256456
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© 2023 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The terms on which this article has been published allow the posting of the Accepted Manuscript in a repository by the author(s) or with their consent.
https://creativecommons.org/licenses/by/4.0/
© 2023 The Author(s). Published by Informa UK Limited, trading as Taylor & Francis Group. This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The terms on which this article has been published allow the posting of the Accepted Manuscript in a repository by the author(s) or with their consent.
https://creativecommons.org/licenses/by/4.0/
Julkaisun pysyvä osoite on
https://urn.fi/URN:NBN:fi-fe20230913124292
https://urn.fi/URN:NBN:fi-fe20230913124292
Tiivistelmä
Abstract
In this study, cost-effective alkali-activated materials made from industrial side streams (blast furnace slag and Na-jarosite) were developed for catalytic applications. The catalytic activity of the prepared materials was examined in catalytic wet peroxide oxidation reactions of a bisphenol A in an aqueous solution. All materials prepared revealed porous structure and characterisation expressed the incorporation of iron to the material via ion exchange in the preparation step. Furthermore, the materials prepared exhibited high specific surface areas (over 200 m2/g) and were mainly mesoporous. Moderate bisphenol A removal percentages (35%–37%) were achieved with the prepared materials during 3 h of oxidation at pH 7–8 and 50°C. Moreover, the activity of catalysts remained after four consecutive cycles (between the cycles the catalysts were regenerated) and the specific surface areas decreased only slightly and no changes in the phase structures were observed. Thus, the prepared blast furnace slag and Na-jarosite-based catalysts exhibited high mechanical stability and showed good potential in the removal of bisphenol A from wastewater through catalytic wet peroxide oxidation.
In this study, cost-effective alkali-activated materials made from industrial side streams (blast furnace slag and Na-jarosite) were developed for catalytic applications. The catalytic activity of the prepared materials was examined in catalytic wet peroxide oxidation reactions of a bisphenol A in an aqueous solution. All materials prepared revealed porous structure and characterisation expressed the incorporation of iron to the material via ion exchange in the preparation step. Furthermore, the materials prepared exhibited high specific surface areas (over 200 m2/g) and were mainly mesoporous. Moderate bisphenol A removal percentages (35%–37%) were achieved with the prepared materials during 3 h of oxidation at pH 7–8 and 50°C. Moreover, the activity of catalysts remained after four consecutive cycles (between the cycles the catalysts were regenerated) and the specific surface areas decreased only slightly and no changes in the phase structures were observed. Thus, the prepared blast furnace slag and Na-jarosite-based catalysts exhibited high mechanical stability and showed good potential in the removal of bisphenol A from wastewater through catalytic wet peroxide oxidation.
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