Ultrafast Nuclear Magnetic Resonance as a Tool to Detect Rapid Chemical Change in Solution
Tickner, Ben J.; Singh, Kawarpal; Zhivonitko, Vladimir V.; Telkki, Ville-Veikko (2024-07-24)
American chemical society
24.07.2024
Tickner, Ben. J., Singh, K., Zhivonitko, V. V., & Telkki, V.-V. (2024). Ultrafast nuclear magnetic resonance as a tool to detect rapid chemical change in solution. ACS Physical Chemistry Au, 4(5), 453–463. https://doi.org/10.1021/acsphyschemau.4c00042
https://creativecommons.org/licenses/by/4.0/
© 2024 The Authors. Published by American Chemical Society. This publication is licensed under CC-BY 4.0 .
https://creativecommons.org/licenses/by/4.0/
© 2024 The Authors. Published by American Chemical Society. This publication is licensed under CC-BY 4.0 .
https://creativecommons.org/licenses/by/4.0/
Julkaisun pysyvä osoite on
https://urn.fi/URN:NBN:fi:oulu-202408145428
https://urn.fi/URN:NBN:fi:oulu-202408145428
Tiivistelmä
Abstract
Ultrafast nuclear magnetic resonance (NMR) uses spatial encoding to record an entire two-dimensional data set in just a single scan. The approach can be applied to either Fourier-transform or Laplace-transform NMR. In both cases, acquisition times are significantly shorter than traditional 2D/Laplace NMR experiments, which allows them to be used to monitor rapid chemical transformations. This Perspective outlines the principles of ultrafast NMR and focuses on examples of its use to detect fast molecular conversions in situ with high temporal resolution. We discuss how this valuable tool can be applied in the future to study a much wider variety of novel reactivity.
Ultrafast nuclear magnetic resonance (NMR) uses spatial encoding to record an entire two-dimensional data set in just a single scan. The approach can be applied to either Fourier-transform or Laplace-transform NMR. In both cases, acquisition times are significantly shorter than traditional 2D/Laplace NMR experiments, which allows them to be used to monitor rapid chemical transformations. This Perspective outlines the principles of ultrafast NMR and focuses on examples of its use to detect fast molecular conversions in situ with high temporal resolution. We discuss how this valuable tool can be applied in the future to study a much wider variety of novel reactivity.
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