Probing the magnetic and magneto-optical properties of a radical-bridged Tb4 single-molecule magnet
Mavragani, Niki; Kitos, Alexandros A; Gálico, Diogo A; Mansikkamäki, Akseli; Murugesu, Muralee (2023-10-30)
Royal society of chemistry
30.10.2023
Chem. Commun., 2023,59, 13970-13973
https://rightsstatements.org/vocab/InC/1.0/
© The Royal Society of Chemistry 2023
https://rightsstatements.org/vocab/InC/1.0/
© The Royal Society of Chemistry 2023
https://rightsstatements.org/vocab/InC/1.0/
Julkaisun pysyvä osoite on
https://urn.fi/URN:NBN:fi:oulu-202401031037
https://urn.fi/URN:NBN:fi:oulu-202401031037
Tiivistelmä
Abstract
Reaction of the 1,2,4,5-tetrazine (tz˙−) radical and {Cp*2Tb}+ has yielded a tetranuclear radical-bridged TbIII single-molecule magnet. The strong Ln–radical coupling and the electronic differences of the TbIII ions in [(Cp*2Tb)4(tz˙−)4]·3C6H6 (1) are probed via magnetic, magneto-optical and computational studies.
Reaction of the 1,2,4,5-tetrazine (tz˙−) radical and {Cp*2Tb}+ has yielded a tetranuclear radical-bridged TbIII single-molecule magnet. The strong Ln–radical coupling and the electronic differences of the TbIII ions in [(Cp*2Tb)4(tz˙−)4]·3C6H6 (1) are probed via magnetic, magneto-optical and computational studies.
Kokoelmat
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