Cleansing effect during the TBAOH treatment of ultra-stable zeolite Y
Gackowski, Mariusz; Selent, Anne; Ainasoja, Ilari; Mazur, Michal; Hunger, Michael; Datka, Jerzy; Telkki, Ville-Veikko (2023-04-29)
Elsevier
29.04.2023
Gackowski, M., Selent, A., Ainasoja, I., Mazur, M., Hunger, M., Datka, J., & Telkki, V.-V. (2023). Cleansing effect during the TBAOH treatment of ultra-stable zeolite Y. Microporous and Mesoporous Materials, 359, 112626. https://doi.org/10.1016/j.micromeso.2023.112626
https://creativecommons.org/licenses/by-nc-nd/4.0/
© 2023. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/
https://creativecommons.org/licenses/by-nc-nd/4.0/
© 2023. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/
https://creativecommons.org/licenses/by-nc-nd/4.0/
Julkaisun pysyvä osoite on
https://urn.fi/URN:NBN:fi:oulu-202401021033
https://urn.fi/URN:NBN:fi:oulu-202401021033
Tiivistelmä
Abstract
Ultrastabilization of zeolites is performed by an intense treatment: high-temperature steaming with further acid leaching to obtain a stable and very catalytically active material. This work shows that ultra-stable zeolite Y (USY) possesses small particles of amorphous material located in the porous structure, as detected via 29Si MAS NMR and STEM. They are washed out by the chemical treatment with 0.2 M TBAOH without deterioration or modification of the crystal structure of zeolite. Contrarily, the treatment of this zeolite with NaOH-containing solutions, results in major changes in porosity and acidity of the samples. TBAOH-treated sample showed significantly different NMR spectra of adsorbed 129Xe, containing two separate signals and powder-like line shapes recorded at low temperatures. It was ascribed to the higher loading of xenon atoms in supercages. The cleaning of the sample from the debris located in micropores increases the accessible volume in supercages, therefore xenon atoms could occupy the cages in higher quantities. This treatment method could be used for fine-tuning of ultra-stable zeolite Y crystals.
Ultrastabilization of zeolites is performed by an intense treatment: high-temperature steaming with further acid leaching to obtain a stable and very catalytically active material. This work shows that ultra-stable zeolite Y (USY) possesses small particles of amorphous material located in the porous structure, as detected via 29Si MAS NMR and STEM. They are washed out by the chemical treatment with 0.2 M TBAOH without deterioration or modification of the crystal structure of zeolite. Contrarily, the treatment of this zeolite with NaOH-containing solutions, results in major changes in porosity and acidity of the samples. TBAOH-treated sample showed significantly different NMR spectra of adsorbed 129Xe, containing two separate signals and powder-like line shapes recorded at low temperatures. It was ascribed to the higher loading of xenon atoms in supercages. The cleaning of the sample from the debris located in micropores increases the accessible volume in supercages, therefore xenon atoms could occupy the cages in higher quantities. This treatment method could be used for fine-tuning of ultra-stable zeolite Y crystals.
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- Avoin saatavuus [38697]
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