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From Norway spruce bark to carbon foams : characterization, and applications

Varila, Toni; Brännström, Hanna; Kilpeläinen, Petri; Hellström, Jarkko; Romar, Henrik; Nurmi, Juha; Lassi, Ulla (2020-04-01)

 
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https://doi.org/10.15376/biores.15.2.3651-3666

Varila, Toni
Brännström, Hanna
Kilpeläinen, Petri
Hellström, Jarkko
Romar, Henrik
Nurmi, Juha
Lassi, Ulla
North Carolina State University
01.04.2020

Varila, T., Brännström, H., Kilpeläinen, P., Hellström, J., Romar, H., Nurmi, J., and Lassi, U. (2020) From Norway spruce bark to carbon foams : characterization, and applications. BioResources 15(2), 3651-3666. doi:10.15376/biores.15.2.3651-3666

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BioResources follows an open-access policy of publication. Research articles, scholarly reviews, and editorial items accepted for publication by BioResources will be made available for viewing and download, without restriction and without charge, to users of the Internet. Such users are entitled to fair use of the material for research and educational purposes, but they do not have permission to publish or to sell the material or to quote it without attribution. The author(s) retain rights to use the submitted and published material without restriction.
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doi:https://doi.org/10.15376/biores.15.2.3651-3666
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https://urn.fi/URN:NBN:fi-fe2020052639148
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Abstract

Fresh bark from spruce Picea abies was milled and extracted with hot water. The extracts were purified in a number of steps in order to get tannin-extracts pure enough to prepare tannin-based carbon foams. The chemical composition of the extracts were analyzed. The foams were maturated and thermally treated to obtain desired properties, such as specific surface area, porosity, and compressive strength. It was possible to produce carbon foams even if they contained carbohydrate impurities. Differences in the properties of the carbon foams such as compressive strength, specific surface areas, and pore size distributions might be related to the compositions of the extracts. The foams were finally activated chemically and physically and were tested in adsorption of methylene blue. Results from the adsorption tests showed that adsorption was highly related to the total pore volume and the amount of mesopores created inside the foam structure during the thermal treatment.

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