Conductive hybrid filaments of carbon nanotubes, chitin nanocrystals and cellulose nanofibers formed by interfacial nanoparticle complexation
Zhang, Kaitao; Ketterle, Lukas; Järvinen, Topias; Hong, Shu; Liimatainen, Henrikki (2020-02-21)
Kaitao Zhang, Lukas Ketterle, Topias Järvinen, Shu Hong, Henrikki Liimatainen, Conductive hybrid filaments of carbon nanotubes, chitin nanocrystals and cellulose nanofibers formed by interfacial nanoparticle complexation, Materials & Design, Volume 191, 2020, 108594, ISSN 0264-1275, https://doi.org/10.1016/j.matdes.2020.108594
© 2020 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
https://creativecommons.org/licenses/by-nc-nd/4.0/
https://urn.fi/URN:NBN:fi-fe202003168241
Tiivistelmä
Abstract
In this paper, anionic TEMPO-oxidized cellulose nanofibers (TO-CNFs) and cationic, partially deacetylated, chitin nanocrystals (ChNCs) were used to fabricate continuous composite filaments (TO-CNF/ChNC filament) with a straightforward and sustainable aqueous process based on the interfacial nanoparticle complexation (INC) of oppositely charged nano-constituents. In particular, the role of TO-CNF and ChNC concentrations in filament drawing and the effect of drawing speed on the mechanical properties of composite filaments were investigated. Moreover, conductive filaments were fabricated by mixing single walled carbon nanotubes (SWCNTs) with TO-CNF dispersion and further complexing with the ChNC aqueous suspension. A conductive filament with an electrical conductivity of 2056 S/m was obtained. However, the increase in the SWCNTs content reduced the mechanical properties of the formed filament compared to neat TO-CNF/ChNC filament. This study not only introduces a new nanoparticle candidate to prepare filaments based on INC method but also provides potential advanced and alternative green filament to be used as wearable electronics in biomedical area.
Kokoelmat
- Avoin saatavuus [34166]
