Ultralow loss CaMgGeO₄ microwave dielectric ceramic and its chemical compatibility with silver electrodes for low-temperature cofired ceramic applications

Abstract

<div lang="en" class="abs"><p class="abs_header">Abstract</p><p>A new ultralow dielectric loss cofired CaMgGeO₄ dielectric material with olivine structure was fabricated by the solid-state route. The X-ray patterns, Rietveld refinement, and microstructure revealed the characteristics of the synthesized material. CaMgGeO₄ ceramic belongs to the orthorhombic system with a <em>Pbmn</em> space group. Sintered at 1300 °C for 6 h, the ceramic exhibited a densification of 96.5%, an ultrahigh quality factor (Q × <em>f</em>) of 124 900 GHz (tan δ = 1.24 × 10^–4) at a frequency of 15.5 GHz, a permittivity (ε_r) of 6.71, and a temperature coefficient of resonant frequency (τ_f) of −73.7 ppm/°C, and the average coefficient of thermal expansion of CaMgGeO₄ was 12.4 ppm/°C. The sintering temperature of the CaMgGeO₄ ceramic was reduced from 1300 to 940 °C with the addition of 5 wt % B₂O₃. The CaMgGeO₄ + 5 wt % B₂O₃ ceramics exhibited favorable microwave dielectric performances: Q × <em>f</em> = 102 000 GHz (at 16.4 GHz), ε_r = 5.80, and τ_f = −64.7 ppm/°C, respectively. In addition, the CaMgGeO₄ ceramic did not react with Ag electrodes, which could be advantageous in low-temperature cofired ceramic multilayer microwave devices.</p></div>