Probing RbBr solvation in freestanding sub-2nm water clusters

Hautala, Lauri; Jänkälä, Kari; Mikkelä, Mikko-Heikki; Turunen, Paavo; Prisle, Nønne L.; Patanen, Minna; Tchaplyguine, Maxim; Huttula, Marko (2017-09-04)
 
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URL:
https://doi.org/10.1039/C7CP04398H

Hautala, Lauri
Jänkälä, Kari
Mikkelä, Mikko-Heikki
Turunen, Paavo
Prisle, Nønne L.
Patanen, Minna
Tchaplyguine, Maxim
Huttula, Marko
Royal Society of Chemistry
04.09.2017

Hautala, L., Jänkälä, K., Mikkelä, M., Turunen, P., Prisle, N., Patanen, M., Tchaplyguine, M., Huttula, M. (2017) Probing RbBr solvation in freestanding sub-2 nm water clusters. Physical Chemistry Chemical Physics, 19 (36), 25158-25167. doi:10.1039/C7CP04398H

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doi:https://doi.org/10.1039/C7CP04398H
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https://urn.fi/URN:NBN:fi-fe201803296278
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Abstract

Concentration dependent solvation of RbBr in freestanding sub-2 nm water clusters was studied using core level photoelectron spectroscopy with synchrotron radiation. Spectral features recorded from dilute to saturated clusters indicate that either solvent shared or contact ion pairs are present in increasing amount when the concentration exceeds 2 mol kg−1. For comparison, spectra from anhydrous RbBr clusters are also presented.

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